| 2026 | Yehor Yakushenko | U20 | GR | 97 kg | U20 World Championships |
| 2025 | Alla Belinska | Senior | WW | 72 kg | Senior World Championships |
| 2025 | Nadiia Sokolovska | U20 | — | 76 kg | U20 World Championships |
| 2024 | Iryna Bondar | U20 | — | 62 kg | U20 World Championships |
| 2023 | Alina Filipovych | Senior | WW | 57 kg | World Championships |
| 2023 | Solomiia Vynnyk | U23 | WW | 59 kg | U23 World Championships |
| 2020 | Zhan Beleniuk | Senior | GR | 87 kg | 2020 Summer Olympics |
| 2019 | Zhan Beleniuk | Senior | — | 87 kg | World Championships 2019 - Seniors |
| 2018 | Alla Cherkasova | Senior | — | 68 kg | World Championships 2018 - Seniors |
| 2015 | Oksana Herhel | Senior | — | 60 kg | 2015 World Wrestling Championships |
| 2015 | Zhan Beleniuk | Senior | — | 85 kg | 2015 World Wrestling Championships |
| 2014 | Tkach Yuliya | Senior | WW | 63 kg | World Championships |
| 2013 | Alina Stadnik Makhinia | Senior | WW | 67 kg | World Championships (Budapest) |
| 2013 | Anastasia Osniach Shustova | Senior | WW | 70 kg | World Championships (Zrenjanin) |
| 2013 | Andrey Yatsenko | Senior | FS | 54 kg | World Championships (Zrenjanin) |
| 2013 | Emin Safershaev | Senior | GR | 42 kg | World Championships (Zrenjanin) |
| 2013 | Ibragim Aldatov | Senior | FS | 84 kg | World Championships (Budapest) |
| 2013 | Oksana Livach | Senior | WW | 38 kg | World Championships (Zrenjanin) |
| 2012 | Artur Politaev | Senior | GR | 42 kg | World Championships (Baku) |
| 2012 | Olena Nasibova | Senior | WW | 40 kg | World Championships (Baku) |
| 2011 | Anna Vasilenko | Senior | WW | 59 kg | World Championships (Istanbul) |
| 2011 | Maria Georgieva | Senior | WW | 40 kg | World Championships (Szombathely) |
| 2010 | Aleksandra Kogut | Senior | WW | 51 kg | World Championships (Moscow) |
| 2010 | Alina Stadnik Makhinia | Senior | WW | 67 kg | World Championships (Budapest) |
| 2010 | Igor Didyk | Senior | GR | 120 kg | World Championships (Budapest) |
| 2010 | Muradin Kushkhov | Senior | FS | 120 kg | World Championships (Budapest) |
| 2009 | Alina Stadnik Makhinia | Senior | WW | 67 kg | World Championships (Ankara) |
| 2009 | Yuliia Khavaldzhy Blahinya | Senior | WW | 55 kg | World Championships (Ankara) |
| 2007 | Andriitsev Valerii | Senior | FS | 96 kg | World Championships (Beijing) |
| 2007 | Yulia Tkach Ostapchuk | Senior | WW | 63 kg | World Championships (Beijing) |
| 2006 | Ibragim Aldatov | Senior | FS | 74 kg | World Championships (Guangzhou) |
| 2006 | Vladimir Shatskikh | Senior | GR | 74 kg | World Championships (Guangzhou) |
| 2005 | Aleksandra Kogut | Senior | WW | 51 kg | World Championships (Vilnius) |
| 2005 | Mariya Stadnik | Senior | WW | 44 kg | World Championships (Vilnius) |
| 2004 | Elbrus Tedieiev | Senior | FS | 66 kg | 2004 Summer Olympics |
| 2004 | Iryna Merleni | Senior | WW | 48 kg | 2004 Summer Olympics |
| 2003 | Irina Melnik-Merleni | Senior | WW | 48 kg | World Championships (New York) |
| 2003 | Lyudmila Balushka | Senior | WW | 44 kg | World Championships (Istanbul) |
| 2002 | Elbrus Tedeev | Senior | FS | 66 kg | World Championships (Tehran) |
| 2002 | Katerina Burmistrova | Senior | WW | 67 kg | World Championships (Chalkida) |
| 2001 | Irina Melnik-Merleni | Senior | WW | 46 kg | World Championships (Sofia) |
| 2000 | Armen Vardanyan | Senior | GR | 63 kg | World Championships (Nantes) |
| 2000 | Irina Melnik-Merleni | Senior | WW | 46 kg | World Championships (Sofia) |
| 2000 | Ivan Ishchenko | Senior | FS | 130 kg | World Championships (Nantes) |
| 2000 | Sergey Rutenko | Senior | GR | 85 kg | World Championships (Nantes) |
| 2000 | Vladimir Shatskikh | Senior | GR | 69 kg | World Championships (Nantes) |
| 1999 | Elbrus Tedeev | Senior | FS | 63 kg | World Championships (Ankara) |
| 1999 | Irina Melnik-Merleni | Senior | WW | 46 kg | World Championships (Bucharest) |
| 1999 | Maksym Podolcky | Senior | GR | 58 kg | World Championships (Nykobing Falster) |
| 1998 | Irina Melnik-Merleni | Senior | WW | 46 kg | World Championships (Manchester) |
| 1998 | Sergios Solonikis | Senior | GR | 70 kg | World Championships (Cairo) |
| 1997 | Parviz Kasimov | Senior | GR | 56 kg | World Championships (Turku) |
| 1996 | Alexander Daragan | Senior | GR | 81 kg | World Championships (Walbrzych) |
| 1996 | David Saldadze | Senior | GR | 88 kg | World Championships (Walbrzych) |
| 1996 | Michael Shvidkiy | Senior | GR | 95 kg | World Championships (Tehran) |
| 1996 | Sergej Sobokar | Senior | GR | 50 kg | World Championships (Walbrzych) |
| 1996 | V'iacheslav Oliynyk | Senior | GR | 90 kg | 1996 Summer Olympics |
| 1995 | Elbrus Tedeev | Senior | FS | 62 kg | World Championships (Atlanta) |
| 1995 | Ilia Stoyanov | Senior | FS | 55 kg | World Championships (Budapest) |
| 1995 | Roustam Adzhi | Senior | GR | 68 kg | World Championships (Prague) |
| 1994 | Olexi Dozogau | Senior | GR | 76 kg | World Championships (Frankfort) |
| 1992 | Alexander Melnik | Senior | FS | 60 kg | World Championships (Istanbul) |
